Composite Processing and Study of Properties for Polypropylene EPD60R/Modified Nanoclay Closite 15A

Document Type: Research Paper

Authors

1 Department of Chemical Engineering, Islamic Azad University, Borujerd Branch, Borujerd, Iran.

2 Chemical Engineering and Petroleum Faculty, Razi University, Kermanshah, Iran

3 Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran

4 Shazand Petrochemical Company Research and Development Unit, Arak, Iran

Abstract

The effects of adding nanoclay to improve the thermal and mechanical properties of polypropylene (PP) copolymers grade, EPD60R, were investigated. To improve the dispersion of the nanoclay in the polymeric matrix, a 30wt % of nanoclay master batch was first prepared by mixing PP matrix maleic anhydride PP oligomer (PP - g - MA) and closite15A(C15A) nanoclay. The prepared master batch was used to produce nanocomposites with 2 and 5wt% nanoclay. The nanocomposites were analyzed by XRD (X- ray diffraction), SEM (Scanning Electron Microscopy), DSC (Differential Scanning Calorimetric), TGA (Thermogravimetric Analysis), and other mechanical tests. XRD and SEM results indicated the occurrence of an intercalated layer structure in the nanocomposites. Thermal properties of the nanocomposites were investigated using DSC and TGA tests. The crystallinity of the 2wt% nanoclay was improved by about 59.23% in the nanoclay reinforced samples. As the content of nanoclay increased, the composite exhibited higher thermal degradation temperature. Performing a limiting oxygen index (LOI) test on the samples showed that the addition of nanoclay to the EPD60R matrix increased the flame retardancy by 12.58%. The tensile modulus of the nanocomposites improved compared to the pure polymer, while the elongation at yield showed a reduction. To investigate the nanocomposite in pipe application, a pipe (external diameter 110.8 and thickness 3.65mm) was manufactured in a special tube extruder machine with 2wt% of C15A. Tests of the tube’s physical and mechanical properties were carried out and indicated that its ring stiffness increased by 25% compared to the pure PP.

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