Investigation of mass transfer coefficients in irregular packed liquid-liquid extraction columns in the presence of various nanoparticles

Vesal, Ali; Rahbar-Kelishami, Ahmad; Mohammadi, Toraj

doi:10.22104/jpst.2017.2233.1084

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	Investigation of mass transfer coefficients in irregular packed liquid-liquid extraction columns in the presence of various nanoparticles
Article 6, Volume 3, Issue 2, Spring 2017, Page 113-120 PDF (956.89 K)
Document Type: Research Paper
DOI: 10.22104/jpst.2017.2233.1084
Authors
Ali Vesal; Ahmad Rahbar-Kelishami ; Toraj Mohammadi
Department of Chemical Engineering, Iran University of Science and Technology (IUST), Tehran, Iran
Abstract
In the present study, the effect of various nanofluids on mass transfer coefficients in an irregular packed liquid-liquid extraction column was investigated. The chemical system of toluene–acetic acid–water was used. 10 nm SiO₂, TiO₂ and ZrO₂ nanoparticles with various concentrations were dispersed in toluene-acid acetic to provide nanofluids. The influence of concentration and hydrophobicity/hydrophilicity of nanoparticle on mass transfer coefficient was discussed. The experimental results show that the mass transfer coefficient enhancement depends on the kind and the concentration of nanoparticles. The maximum enhancement of 35%, 245% and 207% was achieved for 0.05 vol% of SiO₂, TiO₂ and ZrO₂ nanofluids, respectively. A new conceptual model was proposed for prediction of the effective diffusivity as a function of nanoparticle concentration, drop size and drop Reynolds number.
Highlights
In this study, the effect of various nanoparticles on the mass transfer coefficient was investigated. Maximum enhancements in mass transfer coefficient of 35%, 245% and 207% were achieved in the presence of SiO₂, TiO₂ and ZrO₂, respectively. A new conceptual model was proposed for prediction of the effective diffusivity as a function of nanoparticle concentration, drop size and drop Reynolds number with a high accuracy.
Keywords
Liquid-liquid extraction; nanoparticles; Mass transfer coefficient; Hydrophobic; Hydrophilic


References
[1] R. Saidura, K.Y. Leongb, H.A. Mohammad, A review onapplications and challenges of nanofluids, Renew. Sust. Energ. Rev. 15 (2011) 1646-1668. [2] S. Krishnamurthy, P. Bhattacharya, P.E. Phelan, R.S. Prasher, Enhanced mass transport in nanofluids, Nano Lett. 6 (2006) 419-42. [3] B. Olle, S. Bucak, T.C. Holmes, L. Bromberg, T.A. Hatton, D.I.C. Wang, Enhancement of oxygen mass transfer using functionalized magnetic nanoparticles, Ind. Eng. Chem. Res., 45 (2006) 4355-4363. [4] H. Zhu, B.H. Shanks, T.J. Heindel, Enhancing CO-water mass transfer by functionalized MCM-41 nanoparticles, Ind. Eng. Chem. Res. 47 (2008) 7881-7887. [5] X. Fang, Y. Xuan, Q. Li, Experimental investigation on enhanced mass transfer in nanofluids, Appl. Phys. Lett. 95 (2009) 203108. [6] J. Veilleux, S. Coulombe, A total internal reflection fluorescence microscopy study of mass diffusion enhancement in water-based alumina nanofluids, Appl. Phys. 108 (2010) 104316-104318. [7] J.K. Lee, J. Koo, H. Hong, Y.T. Kang, The effects of nanoparticles on absorption heat and mass transfer performance in NH3/H2O binary nanofluids, Int. J. Refrig. 33 (2010) 269-275. [8] C. Pang, W. Wub, W. Sheng, H. Zhang, Y.T. Kang, Mass transfer enhancement by binary nanofluids (NH3/H2O + Ag nanoparticles) for bubble absorption process, In. J. Refrig. 35 (2012) 2240-2247. [9] I.T. Pineda, J.W. Lee, I. Jung, Y.T. Kang, CO2 absorption enhancement by methanol-based Al2O3 and SiO2 nanofluids in a tray column absorber, Int. J. Refrig. 35 (2012) 1402-1409. [10] H. Beiki, M. Nasr Esfahany, N. Etesami, Laminar forced convective mass transfer of g-Al2O3/electrolyte nanofluid in a circular tube, Int. J. Therm. Sci. 64 (2013) 251-256. [11] H. Beiki, M. Nasr Esfahany, N. Etesami, Turbulent mass transfer of Al2O3 and TiO2 electrolyte nanofluids in circular tube, Microfluid. Nanofluid. 15 (2013) 501-508. [12] A. Bahmanyar, N. Khoobi, M.R. Mozdianfard, H. Bahmanyar, The influence of nanoparticles on hydrodynamic characteristics and mass transfer performance in a pulsed liquid-liquid extraction column, Chem. Eng. Process. 50 (2011) 1198-1206. [13] A. Bahmanyar; N. Khoobi, M.M.A. Moharrer, H. Bahmanyar, Mass transfer from nanofluid drops in a pulsed liquid-liquid extraction column, Chem. Eng. Res. Des. 92 (2014) 2313-2323. [14] J. Saien, H. Bamdadi, Mass transfer from nanofluid single drops in liquid-liquid extraction process, Ind. Eng. Chem. Res. 51 (2012) 5157-5166. [15] J. Saien, H. Bamdadi, Sh. Daliri, Liquid-liquid extraction intensification with magnetite nanofluid single drops under oscillating magnetic field, Ind. Eng. Chem, 21, 1152–1159. [16] A. Rahbar-Kelishami, S.N. Ashrafizadeh, M. Rahnamaee, The effect of type and concentration of nano-particles on the mass transfer coefficients: experimental and Sherwood number correlating, Sep. Sci. Technol. 50 (2015) 1776-1784. [17] A. Rahbar, Z. Azizi, H. Bahmanyar, M.A. Moosavian, Prediction of enhancement factor for mass transfer coefficient in regular packed liquid-liquid extraction columns, Can. J. Chem. Eng. 89 (2011) 508-519. [18] R.E. Treybal, Mass transfer operations, 3rd Ed., McGraw Hill, Japan, 1990. [19] A.B. Newman, The drying of porous solids: Diffusions and surface emission equations, T. Am. Inst. Chem. Eng. 27 (1931) 203-220.
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